trans-Bis[bis(2-methoxyphenyl)phenylphosphine-κP]dichloridopalladium(II)
نویسندگان
چکیده
The structure of the title compound, [PdCl(2)(C(20)H(19)O(2)P)(2)], shows a square-planar geometry for the Pd(II) ion within a Cl(2)Pd[PPh(PhOMe)(2)](2) ligand set. The Pd(II) atom sits on an inversion centre and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom and one bis-(2-methoxy-phen-yl)phenyl-phosphine ligand. The trans arrangement of ligands is also imposed by symmetry.
منابع مشابه
[μ-Bis(diphenylarsino)methane-1:2κ2 As:As′][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ3 C,2κ3 C,3κ3 C-triangulo-triruthenium(0) dichloromethane 0.15-solvate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(20)H(19)O(2)P)(CO)(9)]·0.15CH(2)Cl(2), contains one mol-ecule of the triangulo-triruthenium complex and one partially occupied dichloro-methane solvent mol-ecule. The dichloro-methane solvent lies across a crystallographic inversion center leading to the mol-ecule being disordered over two positions of e...
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